Sustainable Shape-Memory Polyurethane from Abietic Acid: Superior Mechanical Properties and Shape Recovery with Tunable Transition Temperatures.

A new chemical architecture from abietic acid, consisting of a cycloaliphatic unsaturated terminal diisocyanate (AADI) structure, is synthesized and fully characterized. The AADI is then used to construct an amorphous and biocompatible shape-memory polyurethane (SMPU) network system with adjustable cross-linking densities over a wide range. The SMPU network exhibits good shape-memory properties with a shape fixing rate of greater than 98 % and a shape recovery rate of 95 %. In vitro hydrolytic biodegradation weight loss ratio of SMPUs reaches 71 % within eight weeks. The physical properties of these SMPUs are comparable to those reported for SMPUs obtained from commercially available petroleum-derived diisocyanates. This is the first time that multiple SMPU networks based on abietic acid have been reported. These environmentally-friendly SMPUs display a wide range of physicomechanical properties with promising hydrolytic degradability, showing good potential for practical application.