The Electrochemical Behavior of Unmodified and Pd-NPs Modified AB 5 Hydrogen Storage Alloy in Selected Protic and Aprotic Ionic Liquids (ILs): Towards ILs-Based Electrolytes for Ni-MH Batteries.

The objective of this work was to study the electrochemical behavior of AB 5 alloy and its composite with Pd nanoparticles in selected ionic liquids. The protic ionic liquid (diethylmethylammonium triflate) and the mixture of aprotic ionic liquid (1-ethyl-3-methylimidazolium methanesulfonate) with parent superacid were used as electrolytes in the process of hydrogen electrosorption in AB 5 alloy electrodes. The impact of the surface modification of AB 5 electrode with Pd nanoparticles has been checked. The studies revealed that the highest hydrogen absorption capacity can be obtained in Pd-NPs-AB 5 electrode in DEMA-TFO. It was found that the surface modification with Pd-NPs facilitates the activation of the electrode and results in stabilization of the plateau potential of discharging. The studies show that more effort should be put into the synthesis of less corrosive tailored ionic liquids suitable to be used as electrolytes in hydride batteries.