A wheel-shaped Dy(iii) single-molecule magnet supported by polyoxotungstates.

Yu HuoYan-Cong Chen Jun-Liang Liu Jian-Hua JiaWen-Bin ChenSi-Guo WuMing-Liang Tong

Published in: Dalton transactions (Cambridge, England : 2003) (2018)

A wheel-shaped Dy(iii) single-molecule magnet (SMM), supported by polyoxotungstates, Cs15K8Na12[K⊂{(AsW9O33)Dy(H2O)2}6]·71H2O (1), is described here. The polyanion of 1 possesses an idealized S6 symmetry. The effective energy barrier (68 K) obtained from magnetic studies is consistent with the deconvolution of the luminescence spectra of 1.

Keyphrases

single molecule
atomic force microscopy
living cells
quantum dots
molecularly imprinted
density functional theory
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