Hydride-Transfer Reaction to a Mononuclear Manganese(III) Iodosylarene Complex.
Donghyun JeongJaeheung ChoPublished in: Inorganic chemistry (2021)
Metal iodosylarene species have received interest because of their potential oxidative power as a catalyst. We present the first example of hydride-transfer reactions to a mononuclear manganese(III) iodosylbenzene complex, [MnIII(TBDAP)(OIPh)(OH)]2+ (1; TBDAP = N,N-di-tert-butyl-2,11-diaza[3.3](2,6)pyridinophane), with dihydronicotinamide adenine dinucleotide (NADH) analogues. Kinetic studies show that hydride-transfer from the NADH analogues to 1 occurs via a proton-coupled electron transfer, followed by a rapid electron transfer.
Keyphrases
- electron transfer
- peripheral blood
- molecular docking
- ionic liquid
- highly efficient
- room temperature
- escherichia coli
- oxide nanoparticles
- structure activity relationship
- biofilm formation
- pseudomonas aeruginosa
- molecular dynamics simulations
- loop mediated isothermal amplification
- carbon dioxide
- candida albicans
- genetic diversity