Quest for a Desolvated Structure Unveils Breathing Phenomena in a MOF Leading to Greener Catalysis in a Solventless Setup: Insights from Combined Experimental and Computational Studies.
Sarita KumariAnand YadavAnkita KumariSomanath MahapatraDevender KumarJyoti SharmaPreety YadavDibyajyoti GhoshAnindita ChakrabortyPrakash KanooPublished in: Inorganic chemistry (2024)
The crystal structure of the metal-organic framework (MOF), {Mn 2 (1,4-bdc) 2 (DMF) 2 } n ( 1 ) (1,4-bdcH 2 , 1,4-benzenedicarboxylic acid; DMF, N , N -dimethylformamide), is known for a long time; however, its desolvated structure, {Mn 2 (1,4-bdc) 2 } n ( 1' ), is not yet known. The first-principles-based computational simulation was used to unveil the structure of 1' that shows the expansion in the framework, leading to pore opening after the removal of coordinated DMF molecules. We have used 1' that contains open metal sites (OMSs) in the structure in cyanosilylation and CO 2 cycloaddition reactions and recorded complete conversions in a solventless setup. The pore opening in 1' allows the facile diffusion of small aldehyde molecules into the channels, leading to complete conversion. The reactions with larger aldehydes, 2-naphthaldehyde and 9-anthracenecarboxaldehyde, also show 99.9% conversions, which are the highest reported until date in solventless conditions. The in silico simulations illustrate that larger aldehydes interact with Mn(II) OMSs on the surfaces, enabling a closer interaction and facilitating complete conversions. The catalyst shows high recyclability, exhibiting 99.9% conversions in the successive reaction cycles with negligible change in the structure. Our investigations illustrate that the catalyst 1' is economical, efficient, and robust and allows reactions in a solventless greener setup, and therefore the catalysis with 1' can be regarded as "green catalysis".