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Periodic Trends in the Stabilization of Actinyls in Their Higher Oxidation States Using Pyrrophen Ligands.

Abigail Jennifer GYang GaoGeorg SchreckenbachElumalai Varathan
Published in: Inorganic chemistry (2023)
Owing to the prominent existence and unique chemistry of actinyls, their complexation with suitable ligands is of significant interest. The complexation of high-valent actinyl moieties (An = U, Np, Pu and Am) with the acyclic sal-porphyrin analogue called "pyrrophen" (L (1) ) and its dimethyl derivative (L (2) ) with four nitrogen and two oxygen donor atoms was studied using relativistic density functional theory. Based on the periodic trends, the [U V O 2 -L (1) /L (2) ] 1- complexes show shorter bond lengths and higher bond orders that increase across the series of pentavalent actinyl complexes mainly due to the localization of the 5f orbitals. Among the hexavalent complexes, the [U VI O 2 -L (1) /L (2) ] complexes have the shortest bonds. Following the uranyl complex, due to the plutonium turn, the [Am VI O 2 -L (1) /L (2) ] complexes exhibit comparable properties with those of the former. Charge analysis suggests the complexation to be facilitated through ligand-to-metal charge transfer (LMCT) mainly through σ donation. Thermodynamic feasibility of complexation was modeled using hydrated actinyl moieties in aqueous medium and was found to be spontaneous. The dimethylated pyrrophen (L (2) ) shows higher magnitudes of thermodynamic parameters indicating increased feasibility compared to the unsubstituted ligand (L (1) ). Energy decomposition analysis (EDA) along with extended transition-state-natural orbitals for chemical valence theory (ETS-NOCV) analysis shows that the dominant electrostatic contributions decrease across the series and are counteracted by Pauli repulsion. Slight but considerable covalency is provided to hexavalent actinyl complexes by orbital contributions; this was confirmed by molecular orbital (MO) analysis that suggests strong covalency in americyl (VI) complexes. In addition to the pentavalent and hexavalent actinyl moieties, heptavalent actinyl species of neptunyl, plutonyl, and americyl were studied. Beyond the influence of the charges, the geometric and electronic properties point to the stabilization of neptunyl (VII) in the pyrrophen ligand environment, while the others shift to a lower (+VI) and relatively stable OS on complexation.
Keyphrases
  • density functional theory
  • photodynamic therapy
  • ionic liquid