A new family of heterometallic [Cu 6 M 4 ] (M = Gd, Tb, Dy and Y) clusters derived from the combined use of selected pyridyl poly-alcohol ligands.

The combined use of 2-(2-pyridyl)-1,3-propane-diol (pypdH 2 ) and 2-hydroxymethyl-2-(2-pyridyl)-1,3-propane-diol (pyptH 3 ) in Cu 2+ /4f chemistry has afforded a new family of isostructural [Cu 6 M 4 (pypt) 4 (pypdH) 4 (NO 3 ) 8 ] [M = Gd (1), Tb (2), Dy (3), and Y (4)] complexes. These compounds are based on an unprecedented three-layered symmetric [Cu 6 M 4 (μ-OR) 16 ] 8+ structural core, formed from the connection of the metal ions by bridging alkoxide arms of the organic ligands. Direct current magnetic susceptibility studies for complexes 1-3 revealed the presence of dominant ferromagnetic exchange interactions, suggesting the existence of large spin ground state values. Alternating current magnetic studies indicate the presence of slow-magnetic relaxation in 1-3.