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Liquid Nitrogen Sources Assisting Gram-Scale Production of Single-Atom Catalysts for Electrochemical Carbon Dioxide Reduction.

Beibei AnJingsheng ZhouLiangjing DuanXiao LiuGuanyao YuTiegang RenXugeng GuoYuanyuan LiHans ÅgrenLi WangJinglai Zhang
Published in: Advanced science (Weinheim, Baden-Wurttemberg, Germany) (2023)
Developing metal-nitrogen-carbon (M-N-C)-based single-atom electrocatalysts for carbon dioxide reduction reaction (CO 2 RR) have captured widespread interest because of their outstanding activity and selectivity. Yet, the loss of nitrogen sources during the synthetic process hinders their further development. Herein, an effective strategy using 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF 4 ]) as a liquid nitrogen source to construct a nickel single-atom electrocatalyst (Ni-SA) with well-defined Ni-N 4 sites on a carbon support (denoted as Ni-SA-BB/C) is reported. This is shown to deliver a carbon monoxide faradaic efficiency of >95% over a potential of -0.7 to -1.1 V (vs reversible hydrogen electrode) with excellent durability. Furthermore, the obtained Ni-SA-BB/C catalyst possesses higher nitrogen content than the Ni-SA catalyst prepared by conventional nitrogen sources. Importantly, only thimbleful Ni nanoparticles (Ni-NP) are contained in the large-scale-prepared Ni-SA-BB/C catalyst without acid leaching, and with only a slight decrease in the catalytic activity. Density functional theory calculations indicate a salient difference between Ni-SA and Ni-NP in the catalytic performance toward CO 2 RR. This work introduces a simple and amenable manufacturing strategy to large-scale fabrication of nickel single-atom electrocatalysts for CO 2 -to-CO conversion.
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