Shape-Controlled HgTe Colloidal Quantum Dots and Reduced Spin-Orbit Splitting in the Tetrahedral Shape.

Spherical and tetrahedral HgTe colloidal quantum dots (CQDs) are synthesized, and their doping is tuned electrochemically. Compared to spherical dots of a similar volume, the tetrahedral CQDs show a decrease in confinement energy as well as a sharper band edge absorption. The intraband spectra of the tetrahedral CQDs also display a smaller splitting from spin-orbit coupling. The shape-controlled synthesis with an improved size distribution and sharper optical features could find applications in optoelectronic devices.