Discerning the Structure-Photophysical Property Correlation in Zero-Dimensional Antimony(III)-Doped Indium(III) Halide Hybrids.
Alisha Basheer ShamlaDhritismita SarmaDeep Kumar DasVishnu AnilkumarRangarajan BakthavatsalamArup MahataJanardan KunduPublished in: The journal of physical chemistry letters (2024)
Zero-dimensional (0D) metal halide hybrids incorporating optically emissive Sb 3+ dopants have received huge research attention as a result of dopant-based visible emission for lighting and scintillation applications. Indeed, there have been a plethora of reports on Sb 3+ doping of indium halide (In-X)-based 0D hybrids that show strong dopant emission with varied emission wavelengths (λ em ) and photoluminescence quantum yields (PLQYs). However, discerning the structure-luminescence relation in these 0D-doped hybrids remains challenging because it necessitates exquisite synthetic control on the local metal (dopant) halide geometry/site asymmetry. Demonstrated here is synthetic control that allows tuning of the local metal halide geometry of the Sb 3+ dopants in 0D In-X hybrids utilizing five different organic cations. Experimental analysis of the series of Sb 3+ -doped In-X hybrids reveals a strong correlation between the extent of local metal halide geometry distortion and their photophysical properties (λ em and PLQY). Density functional theory calculations of the doped compounds, characterizing ground- and excited-state structural distortions and energetics, reveal the origin of the extent of luminescence behavior. The experimental-computational results reported herein unravel the operative structure-luminescence relation in 0D Sb 3+ -doped In-X hybrids, provide insight into the emission mechanism, and open up avenues toward rational synthesis of strongly emissive materials with desired emission color for targeted applications.