Zeolitic imidazolate frameworks as intrinsic light harvesting and charge separation materials for photocatalysis.

Zeolitic imidazolate frameworks (ZIFs) are a subclass of metal organic frameworks that have attracted considerable attention in the past years and have found many applications including heterogeneous catalysis due to their highly ordered porous structure, large surface area, and structural flexibility. However, ZIFs are largely utilized as simple hosts or passive media for dispersing other catalytically active species, resembling the roles of zeolites in catalysis. In contrast, our recent findings show that ZIFs not only have broad absorption across the UV-visible and near IR spectral region but also have an exceptionally long-lived excited charge separated state, suggesting that ZIFs may be used as intrinsic light harvesting and photocatalytic materials rather than as inert hosts. This Perspective will focus on the recent progress on the fundamental studies of the intrinsic light absorption, charge separation, and photocatalytic properties of ZIFs and will discuss the outlook for future development.