Aerobic oxidative synthesis of benzimidazoles by flavin photocatalysis.

Yuta ShiogaiMarina OkaHazuki MiyakeHiroki Iida

Published in: Organic & biomolecular chemistry (2024)

Flavin photocatalysis were utilised for an aerobic oxidative reaction between arylamines and o -phenylenediamine. This metal-free reaction proceeded in methanol under visible light irradiation and consumed only atmospheric molecular oxygen, providing a novel eco-friendly method for the synthesis of benzimidazoles.

Keyphrases

visible light
high intensity
carbon dioxide
particulate matter
single molecule
electron transfer
radiation therapy
air pollution