Ferromagnetic Double Perovskite Semiconductors with Tunable Properties.

The authors successfully dope the magnetically silent double perovskite semiconductor Sr 2 GaSbO 6  to induce ferromagnetism and tune its bandgap, with Ga 3+ partially substituted by the magnetic trivalent cation Mn 3+ , in a rigid cation ordering with Sb 5+ . The new ferromagnetic semiconducting Sr 2 Ga 1- x Mn x SbO 6  double perovskite, which crystallizes in tetragonal symmetry (space group I4/m) and has tunable ferromagnetic ordering temperature and bandgap, suggests that magnetic ion doping of double perovskites is a productive avenue toward obtaining materials for application in next-generation oxide-based spintronic devices.