Controlling the Emissive Activity in Heterocyclic Systems Bearing C═P Bonds.
Sunandan SarkarJohn D ProtasiewiczBarry D DunietzPublished in: The journal of physical chemistry letters (2018)
The photophysical properties of a series of heteroatom substituted indoles are explored to identify chemical means to control their emissive activity. In particular, we consider impacts of changes in the conjugated backbone, where the C═N bonds of benzoxazoles are replaced by C═P bonds (benzoxaphospholes). The effects of extending the π-conjugation, incorporating various secondary heteroatoms (X-C═P), and enforcing planar rigidity are also examined. Our computational analysis explains the higher fluorescence efficiency observed with extended π-conjugation and highlights the importance of maintaining molecular planarity at both ground- and emissive-state geometries.