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One-pot C-N/C-C bond formation and oxidation of donor-acceptor cyclopropanes with tetrahydroisoquinolines: access to benzo-fused indolizines.

Pallab KarjeeBijoy DebnathSantu MandalSharajit SahaTharmalingam Punniyamurthy
Published in: Chemical communications (Cambridge, England) (2024)
One-pot C-N/C-C bond formation of donor-acceptor cyclopropanes (DACs) with tetrahydroisoquinolines (THIQs) has been achieved to furnish benzo-fused indolizines. These reactions involve a MgI 2 -catalyzed ring opening of DACs and oxidative annulation using Mn(OAc) 3 ·2H 2 O. The substrate scope and functional group diversity are the important practical features.
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