Synthesis of Hybrid Porphyrin(2.1.2.1)s and Their Complexation.
Yuting DongHirofumi MorimotoXiaojuan LvXuehuan MoFeng ChenFan WuNaoki ArataniFengxian QiuSonglin XuePublished in: The Journal of organic chemistry (2024)
Novel hybrid porphyrin(2.1.2.1)s and their boron and copper complexes were synthesized using the "toy bricks" synthetic method. Crystal data, frontier molecular orbital calculations, and electrostatic potential surface maps reveal that hybridization in the porphyrin(2.1.2.1) donor-acceptor unit controls the selective coordination of BF 2 .
Keyphrases
- photodynamic therapy
- energy transfer
- metal organic framework
- electron transfer
- molecular dynamics simulations
- single molecule
- molecular dynamics
- electronic health record
- genome wide
- density functional theory
- big data
- single cell
- quantum dots
- machine learning
- human health
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- risk assessment
- monte carlo
- solar cells
- climate change
- solid state