Ultrafast Laser Enabling Hierarchical Structures for Versatile Superhydrophobicity with Enhanced Cassie-Baxter Stability and Durability.

The controllable and facile fabrication of surface micro/nanostructures with the required dimensions and morphologies is the key to achieving surface superhydrophobicity. With the advantages of being a noncontact, maskless, programmable, and one-step process, ultrafast laser irradiation is a very flexible and adaptive technique for fabricating various microscale, nanoscale, and micro/nanomultiscale surface structures on diverse solids, thus realizing superhydrophobicity on their surfaces. In this feature article, a comprehensive review of our recent research advances on versatile superhydrophobic surfaces enabled by ultrafast lasers is presented from the perspectives of materials, methodologies, and functionalization. The realization of superhydrophobicity and even superamphiphobicity on varied solid surfaces through ultrafast laser treatment and the underlying mechanisms for the wettability transition of ultrafast-laser-processed surfaces from superhydrophilicity to superhydrophobicity will be discussed. For the sake of practical applications, the ultrafast-laser-based strategies for the large-scale and cost-effective fabrication of superhydrophobic surface micro/nanostructures will be introduced. A special focus will be devoted to the enhancement of structural durability and the Cassie-Baxter stability of ultrafast-laser-enabled superhydrophobic surfaces. Beyond that, the achievement of integrated surface functions including remarkable wetting functions such as the directional collection of water droplets and superhydrophobic surfaces simultaneously with unique optical properties will also be presented.