Carbene-Stabilized Dithiolene (L0 ) Zwitterions.

Yuzhong Wang Phuong M Tran Yaoming Xie Pingrong Wei John N Glushka Henry F Schaefer Gregory H Robinson

Published in: Angewandte Chemie (International ed. in English) (2021)

A series of reactions between Lewis bases and an imidazole-based dithione dimer (1) has been investigated. Both cyclic(alkyl)(amino)carbene (CAAC) (2) and N-heterocyclic carbene (NHC) (4), in addition to N-heterocyclic silylene (NHSi) (6), demonstrate the capability to cleave the sulphur-sulphur bonds in 1, giving carbene-stabilized dithiolene (L0 ) zwitterions (3 and 5) and a spirocyclic silicon-dithiolene compound (7), respectively. The bonding nature of 3, 5, and 7 are probed by both experimental and theoretical methods.

Keyphrases

molecular dynamics simulations