Insights into the electronic structure of hydroxyl on Ag(110) under near ambient conditions.

Adsorbed hydroxyl is a key intermediate present in many catalytic reactions and electrochemical processes. In particular, hydroxyl adsorbed on noble metal surfaces has attracted attention due to its role in water-gas shift, selective oxidation of hydrocarbons and water splitting. In this work, from a well-defined oxygen covered Ag(110) surface with O- p (2 × 1) reconstruction, we prepared a fully hydroxylated surface phase in equilibrium with water and oxygen in the gas phase under near ambient conditions. In situ soft X-ray spectroscopy combined with density functional theory revealed distinctive modifications in the electronic structure of the adsorbate layer upon hydroxylation. We show that both the core and valence electronic states of OH adsorbates have higher binding energies relative to the Fermi level than the states for the O adsorbate. The OH orbitals interact with the d band of Ag giving rise to hybridized orbitals with bonding and anti-bonding symmetry, with larger energy splitting than the oxygen adsorbate.