Effects of Ru(ii/iii) redox on the Co(ii) coordination number and magnetic properties of 1D cyanide-bridged Co-Ru compounds.

Xiaoquan ZhuShaodong SuWenhai CaoShengmin HuYuehong WenXintao WuTian-Lu Sheng

Published in: Dalton transactions (Cambridge, England : 2003) (2018)

A new 1D cyanide-bridged Co-Ru compound, {[trans-RuIII(dmap)4(CN)2Co(dipic)(MeOH)](PF6)}n (1a) (dmap = 4-dimethylaminopyridine, dipic = pyridine-2,6-dicarboxylate), and its reduced state, [trans-RuII(dmap)4(CN)2Co(dipic)]n (1b) have been synthesized. Upon the Ru center reduction from iii to ii, the MeOH solvent molecule bound to Co(ii) in 1a is expelled. 1a displays ferrimagnetic properties but 1b is only a paramagnetic compound.

Keyphrases

energy transfer
lymph node metastasis
fluorescent probe
mass spectrometry
quantum dots