Yellow-Orange Emission in Sb 3+ -Doped Hexakis(thiocarbamidium) Hexabromoindium(III) Tribromide.

A luminescent zero-dimensional organic-inorganic hybrid indium halide (TUH) 6 [In 1- x Sb x Br 6 ]Br 3 (TU = thiourea, 0 ≤ x ≤ 0.0998) was synthesized via the solvothermal method. In structures, resolved by single-crystal X-ray diffraction, isolated distorted [InBr 6 ] 3- and [SbBr 6 ] 3- octahedra are linked to organic TUH + cations by intermolecular N-H···Br and N-H···S hydrogen bonds. The crystals were characterized by elemental analysis, TG-DSC, powder X-ray diffraction, FTIR analysis, and steady-state absorption and photoluminescence spectroscopy. (TUH) 6 [In 1- x Sb x Br 6 ]Br 3 exhibits a broadband yellow-orange emission centered at 595-602 nm with a half-width of 141-149 nm (0.48-0.52 eV) and a large Stokes shift of 232-238 nm (1.33-1.35 eV). This emission can be attributed to the self-trapped exciton emission of triplet states of the octahedral anion [SbBr 6 ] 3- or [InBr 6 ] 3- . Two possible emission mechanisms were discussed. Doping with Sb 3+ leads to a significant increase in photoluminescence quantum yield from 25.7 at x = 0 to 48.4% at x = 0.0065, when excited at 365 nm, indicating the potential use of (TUH) 6 [In 1- x Sb x Br 6 ]Br 3 compounds in the field of photonics.