Selective Primary Alcohol Oxidation of Lignin Streams from Butanol-Pretreated Agricultural Waste Biomass.
Isabella PanovicChristopher S LancefieldDarren PhillipsMark J GronnowNicholas James WestwoodPublished in: ChemSusChem (2019)
Chemically modified lignins are important for the generation of biomass-derived materials and as precursors to renewable aromatic monomers. A butanol-based organosolv pretreatment has been used to convert an abundant agricultural waste product, rice husks, into a cellulose pulp and three additional product streams. One of these streams, a butanol-modified lignin, was oxidized at the γ position to give a carboxylic acid functionalized material. Subsequent coupling of the acid with aniline aided lignin characterization and served as an example of the flexibility of this approach for grafting side chains onto a lignin core structure. The pretreatment was scaled up for use on a multi-kilogram scale, a development that enabled the isolation of an anomeric mixture of butoxylated xylose in high purity. The robust and scalable butanosolv pretreatment has been developed further and demonstrates considerable potential for the processing of rice husks.
Keyphrases
- ionic liquid
- heavy metals
- risk assessment
- room temperature
- climate change
- human health
- wastewater treatment
- sewage sludge
- anaerobic digestion
- municipal solid waste
- nitric oxide
- molecularly imprinted
- hydrogen peroxide
- mass spectrometry
- alcohol consumption
- silver nanoparticles
- electron transfer
- low density lipoprotein
- solid phase extraction