Applications of electron microscopic observations to electrochemistry in liquid electrolytes for batteries.

Herein, we review notable points from observations of electrochemical reactions in a liquid electrolyte by liquid-phase electron microscopy (LP-EM). In situ microscopic observations of electrochemical reactions are urgently required, particularly to solve various battery issues. Battery performance is evaluated by various electrochemical measurements of bulk samples. However, it is necessary to understand the physical/chemical phenomena occurring in batteries to elucidate the reaction mechanisms. Thus, in situ microscopic observation is effective for understanding the reactions that occur in batteries. Herein, we focus on two methods, of the liquid phase (scanning) transmission electron microscopy (LP-S/TEM) and liquid phase scanning electron microscopy (LP-SEM), and summarize the advantages and disadvantages of both methods.