The confinement effect of layered double hydroxides on intercalated pyromellitic acidic anions and highly selective uranium extraction from simulated seawater.

Oxygen-rich pyromellitic acidic anions (PMA 4- ) have been intercalated into MgAl-layered double hydroxides to fabricate the MgAl-PMA-LDH (abbr. PMA-LDH) composite exhibiting excellent adsorption performance toward uranium (U(VI)). Benefiting from the large number of functional groups of -COO - , the PMA-LDH displays an extremely large maximum U adsorption capacity ( q Um) of 352 mg g -1 and an ultra-fast sorption rate, reaching uptakes of ∼97% within 30 min and >99% in 1 h at the initial U concentration ( C U0) of 113 ppm. Over a very wide pH range of 5-11, high U removals (>93%) are achieved at C U0 = 105 ppm. Moreover, in the presence of highly concentrated competitive ions, ultra-high selectivity of UO 2 2+ is observed, giving a very large distribution coefficient ( K d ) of ∼10 6 mL g -1 . Moreover, the PMA-LDH exhibits effective capture of UO 2 2+ in contaminated simulated seawater, showing high uptakes of >93% at C U0 ∼ 10 ppm and >98% at C U0 ∼ 100 ppm. The dispersion effect of LDH layers may contribute to the increase of U adsorption capacity, and the confinement effect of LDH is conducive to the improvement of sorption selectivity toward U. The exploration of the interaction mechanism of UO 2 2+ with PMA 4- confined within the LDH gallery offers an important basis for the fabrication of new kinds of organic/inorganic hybrid materials. The PMA-LDH is a highly effective adsorbent which can be applied to uranium extraction from seawater and uranium disposal in nuclear wastewater.