Optimizing Iodine Enrichment through Induced-Fit Transformations in a Flexible Ag(I)-Organic Framework: From Accelerated Adsorption Kinetics to Record-High Storage Density.

Efficient capture and storage of radioactive I 2 is a prerequisite for developing nuclear power but remains a challenge. Here, two flexible Ag-MOFs (FJI-H39 and 40) with similar active sites but different pore sizes and flexibility are prepared; both of them can capture I 2 with excellent removal efficiencies and high adsorption capacities. Due to the more flexible pores, FJI-H39 not only possesses the record-high I 2 storage density among all the reported MOFs but also displays a very fast adsorption kinetic (124 times faster than FJI-H40), while their desorption kinetics are comparable. Mechanistic studies show that FJI-H39 can undergo induced-fit transformations continuously (first contraction then expansion), making the adsorbed iodine species enrich near the Ag(I) nodes quickly and orderly, from discrete I - anion to the dense packing of various iodine species, achieving the very fast adsorption kinetic and the record-high storage density simultaneously. However, no significant structural transformations caused by the adsorbed iodine are observed in FJI-H40. In addition, FJI-H39 has excellent stability/recyclability/obtainability, making it a practical adsorbent for radioactive I 2 . This work provides a useful method for synthesizing practical radioactive I 2 adsorbents.