Three-Dimensional Superlattices Based on Unusual Chalcogenide Supertetrahedral In-Sn-S Nanoclusters.
Wei WangXiang WangJiaxu ZhangHuajun YangMin LuoChaozhuang XueZhi'en LinTao WuPublished in: Inorganic chemistry (2018)
Reported here are two novel metal chalcogenide superlattices built from unusual supertetrahedral TO2-InSnS clusters. With regard to only one previously reported case of a TO2-InS-based 2D-layered structure, such a combination of In-Sn-S components is thought to be reasonable for leading to the first observation of 3D superlattices based on TO2-InSnS clusters. Besides, these title semiconducting materials also display good performance on the electrocatalytic oxygen reduction reaction.