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Two Catalytic Methods of an Asymmetric Wittig [2,3]-Rearrangement.

Maksim OšekaMariliis KimmIvar JärvingKristin LippurTõnis Kanger
Published in: The Journal of organic chemistry (2017)
Two different approaches for asymmetric catalytic Wittig [2,3]-rearrangement were developed. Allyloxymalonate derivatives were converted into homoallyl alcohols via organocatalytic or Ca2+-catalyzed pathways in moderate to high enantioselectivities.
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