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Capture of actinides (Th4+, [UO2]2+) and surrogating lanthanide (Nd3+) in porous metal-organic framework MIL-100(Al) from water: selectivity and imaging of embedded nanoparticles.

Clément FalaiseChristophe VolkringerRaynald GiovineBénédicte PrelotMarielle HuveThierry Loiseau
Published in: Dalton transactions (Cambridge, England : 2003) (2017)
Aluminium-based metal-organic framework MIL-100 was utilized for the capture of actinide ([UO2]2+, Th4+) and lanthanide (Nd3+) cations. The results indicate a very quick sorption process, leading to very high cation uptakes together with selectivity for Th4+.
Keyphrases
  • metal organic framework
  • ionic liquid
  • high resolution
  • structural basis
  • fluorescence imaging
  • mass spectrometry
  • tandem mass spectrometry