Advances of Organosulfur Materials for Rechargeable Metal Batteries.

Battery materials have become a hotspot in the academic research. Organosulfur compounds are considered as a promising class of cathode materials for rechargeable metal batteries. They have attracted increasing attention in recent years after a long-term stagnancy since 1980s. Recent studies have focused on the understanding of redox mechanism of linear organosulfur molecules R-Sn -R with defined structures. In addition, some new organosulfur compounds are developed. The reversible sulfursulfur (SS) bond breakage/formation of organosulfur in batteries makes them applicable as functional materials in batteries. In this review, new organosulfur materials including molecules, polymers, and composites are introduced. In the following, organosulfur-inorganic hybrid materials are discussed, which have shown unique redox process and enhanced battery performance. In the third part, organosulfur additives are used in Li-S batteries, which can improve the formation of solid-electrolyte interphase (SEI) and alter the redox pathways of sulfur cathodes. In the fourth part, organosulfur materials used in other metal batteries are introduced. Lastly, a summary and some perspectives are given. This review presents an overview of the recent advances of organosulfur materials in batteries and provides guidance for the future development of these materials.