Total Synthesis of Millingtonine.
Patrick D BrownAndrew L LawrencePublished in: Angewandte Chemie (International ed. in English) (2016)
Millingtonine is a glycosidic alkaloid that exists as a pair of pseudo-enantiomeric diastereomers. Consideration of the likely biosynthetic origins of this unusual natural product has resulted in the development of a seven-step total synthesis. Results from this synthetic work provide evidence in support of a proposed network of biosynthetic pathways that can account for the formation of several phenylethanoid natural products.
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