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Reciprocally Photovoltaic Light-Emitting Diode Based on Dispersive Perovskite Nanocrystal.

Jiong LiChenghao DuanQiaoyun WenLigang YuanShibing ZouChang ChenWeiguang XieDongxu LinChristopher C S ChanKam Sing WongKeyou Yan
Published in: Small (Weinheim an der Bergstrasse, Germany) (2022)
Integrating highly efficient photovoltaic (PV) function into light-emitting diodes (LEDs) for multifunctional display is of great significance for compact low-power electronics, but it remains challenging. Herein, it is demonstrated that solution engineered perovskite nanocrystals (PNCs, ≈100 nm) enable efficient electroluminescence (EL) and PV performance within a single device through tailoring the dispersity and interface. It delivers the maximum brightness of 490 W sr -1  m -2 at 2.7 V and 23.2% EL external quantum efficiency, a record value for near-infrared perovskite LED, as well as 15.23% PV efficiency, among the highest value for nanocrystal perovskite solar cells. The PV-EL performance is well in line with the reciprocity relation. These all-solution-processed PV-LED devices open up viable routes to a variety of advanced applications, from touchless interactive screens to energy harvesting displays and data communication.
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