Ultrathin covalent and cuprophilic interaction-assembled copper-sulfur monolayer in organic metal chalcogenide for oriented photoconductivity.
Guang-Ning LiuRang-Dong XuMing-Kun LiYiqiang SunMeng-Jie ZhouRui-Yun CaiZuo-Jiang YouXiao-Ming JiangCuncheng LiPublished in: Chemical communications (Cambridge, England) (2022)
We report the thinnest copper sulfur atomic monolayer in an organic copper chalcogenide [Cu(CMP)] n (CMP = 5-chloro-2-mercaptopyridine). The layer features a new type of copper sulfur structure woven by both covalent bond and cuprophilic interaction and shows an intriguing oriented photoconductivity.