Inherently chiral belt-shaped conjugated macrocycles with strong fluorescence and circularly polarized luminescence.
Xu-Sheng DuXiao-Ni HanYing HanChuan-Feng ChenPublished in: Chemical communications (Cambridge, England) (2022)
A pair of inherently chiral belt-shaped conjugated macrocycles were conveniently synthesized starting from 2,7-fluoren[3]arene triflate, and they not only exhibited green fluorescence, but also showed circularly polarized luminescence with a | g lum | of 2.0 × 10 -3 .