Synthesis of a Macrocycle Bearing a Carbon Framework of [16]Cyclophenacene as a Carbon Nanobelt.
Shuangjiang LiKung K WangPublished in: The Journal of organic chemistry (2019)
A synthetic pathway to a functionalized tetrahydro[5]phenacene was developed, which served as a precursor, leading to a dehydrobenzo[32]annulene macrocycle containing four carbon-carbon triple bonds. The high efficiency of the macrocyclization step can be attributed to the structural rigidity of its immediate precursor. Hydrogenation of the four carbon-carbon triple bonds produced a macrocycle bearing a carbon framework of [16]cyclophenacene as the shortest macrocyclic belt-like structure of an (8,8)armchair carbon nanotube.