Chromaticity-Tunable and Thermal Stable Phosphor-in-Glass Inorganic Color Converter for High Power Warm w-LEDs.

In this work, an aluminate silicate garnet phosphor, Y₂Mg₂Al₂Si₂O12:Ce3+ (YMASG:Ce3+), exhibiting strong and broad yellow-orange emission, was successfully synthesized. Attributed to the double cation substitution of YAG:Ce3+, which led to a compression effect, a redshift was observed with respect to YAG:Ce3+. More importantly, a transparent phosphor-in-glass (PiG) sample was obtained by incorporating the phosphor YMASG:Ce3+ into a special low-melting precursor glass. The energy dispersive spectrometer (EDS) mapping analysis of the as-prepared PiG sample indicates that YMASG:Ce3+ was successfully incorporated into the glass host, and its powders were uniformly distributed in glass. The photoluminescence intensity of the PiG sample was higher than that of the powder due to its relatively high thermal conductivity. Additionally, the combination of the PiG sample and a blue high-power chip generated a modular white LED with a luminous efficacy of 54.5 lm/W, a correlated color temperature (CCT) of 5274 K, and a color rendering index (CRI) of 79.5 at 350 mA.