One-step Synthesis and Enhanced Thermoelectric Properties of Polymer-Quantum Dot Composite Films.

Conventional syntheses of polymer-inorganic composite thermoelectric materials suffer major problems such as inhomogeneity, large particle size, and oxidation that result in ineffective loading. Now a one-step synthesis can be used to fabricate high-quality small-sized anions codoped poly(3,4-ethylenedioxythiophene):dodecylbenzenesulfonate/Cl-tellurium (PEDOT:DBSA/Cl-Te) composite films using a series of novel TeIV -based oxidants. The synchronized production of PEDOT and Te results in thick and homogeneous films containing evenly distributed and well-protected Te quantum dots. Owing to the heavily doped crystalline polymer matrix as well as the <5 nm unoxidized Te quantum dot loading, at low Te concentrations as 2.1-5.8 wt %, the films exhibits high power factors of about 100 μW m-1  K-2 , which is 50 % higher compared to a pure PEDOT:DBSA film.