High quantum yield photochemical water oxidation using a water-soluble cobalt phthalocyanine as a homogenous catalyst.

Takashi NakazonoNagisa AminoRisa MatsudaDaichi Sugawara Tohru Wada

Published in: Chemical communications (Cambridge, England) (2022)

We demonstrated high catalytic activity (TON = 670, TOF max = 2.7 s -1 ) of a water-soluble cobalt phthalocyanine complex (CoPcTS, PcTS = phthalocyaninetetrasulfonate) for visible light-driven photochemical water oxidation and investigated its reaction mechanism by electrochemical and spectroscopic measurements.

Keyphrases

water soluble
visible light
photodynamic therapy
reduced graphene oxide
gold nanoparticles
ionic liquid
electron transfer
ms ms
hydrogen peroxide
molecular docking
molecular dynamics
nitric oxide
atomic force microscopy
molecularly imprinted
room temperature