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Hydrolysis Batteries: Generating Electrical Energy during Hydrogen Absorption.

Rui XiaoJun ChenKai FuXinyao ZhengTeng WangXingguo LiXingguo Li
Published in: Angewandte Chemie (International ed. in English) (2018)
The hydrolysis reaction of aluminum can be decoupled into a battery by pairing an Al foil with a Pd-capped yttrium dihydride (YH2 -Pd) electrode. This hydrolysis battery generates a voltage around 0.45 V and leads to hydrogen absorption into the YH2 layer. This represents a new hydrogen absorption mechanism featuring electrical energy generation during hydrogen absorption. The hydrolysis battery converts 8-15 % of the thermal energy of the hydrolysis reaction into usable electrical energy, leading to much higher energy efficiency compared to that of direct hydrolysis.
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