Superstructured metallocorroles for electrochemical CO2 reduction.
Woormileela SinhaAtif MahammedNatalia FridmanYael Diskin-PosnerLinda J W ShimonZeev GrossPublished in: Chemical communications (Cambridge, England) (2019)
Cobalt and iron complexes of corroles with tyrosine-like proton-transfer-relay moieties in proximity to the metal center have been prepared and fully characterized. The (nitrosyl)iron complex performs very well as an electrocatalyst for the reduction of CO2 to CO.