Fast and reversible solvent-vapor-induced 1D to 2D transformation in emissive Ag(I)-organic networks.
Maxim I RogovoyMariana I RakhmanovaEvgeniy H SadykovGia M CarignanIrina Yu BagryanskayaJing LiAlexander V Artem'evPublished in: Chemical communications (Cambridge, England) (2023)
We report here an unprecedentedly fast and reversible transformation between 1D and 2D MOFs/CPs induced through organic solvent vapours. The transformations occur at room temperature in just 15-20 min, accompanied by a significant change in the observed phosphorescence. These findings provide a new insight into the design of luminescent networks with stimuli-switchable dimensionality.