Polyoxometalate-based crystalline materials as a highly sensitive electrochemical sensor for detecting trace Cr(vi).
Xing XinNa HuYuan-Yuan MaYali WangLin HouHeng ZhangZhan-Gang HanPublished in: Dalton transactions (Cambridge, England : 2003) (2020)
It is crucial to find a convenient and sensitive method for quantitative determination of heavy metal chromium(vi) ions. Developing crystalline materials coupled with polyoxometalates as an electrochemical sensor is a promising approach to address the above issues. Here we reported two reductive polyoxometalate-based crystalline compounds with the formula of (H2bpp)2[Na4Fe(H2O)7][Fe(P4Mo6O31H6)2]·2H2O (1) and (H2bpp)6(bpp)2[Fe(P4Mo6O31H8)2]2·13H2O (2) (bpp = 1,3-bi(4-pyridyl)propane). Structural analysis indicated that both two compounds were composed of inorganic polyanionic clusters and organic protonated bpp cations. The difference lies in the arrangement mode of the inorganic moiety: crystal 1 shows a unique three-dimensional (3-D) inorganic porous skeleton, while crystal 2 consists of isolated 0-D polyanionic clusters. When used as electrochemical sensors in the determination of trace Cr(vi), crystal 1 shows a broad linearity range (2-2610 μM) with a low limit of detection (LOD) of 0.174 μM (9 ppb), which is superior to that of compound 2 (a LOD of 0.33 μM) and meets the standard of Cr(vi) in drinking water set by the WHO (less than 0.962 μM or 50 ppb). Importantly, crystal 1 showed benign selectivity to Cr(vi) in the presence of various heavy metal ions and good reproducibility in a real water sample, which prove its strong anti-interference ability. In addition, experimental results showed that the spatial arrangement of polyanionic clusters could affect the final electrochemical behavior of crystalline materials. This work provides some insights into the design of cost-effective POM-based electrochemical sensors at the molecular level.
Keyphrases
- molecularly imprinted
- heavy metals
- label free
- ionic liquid
- drinking water
- gold nanoparticles
- room temperature
- solid phase extraction
- health risk assessment
- metal organic framework
- health risk
- water soluble
- aqueous solution
- risk assessment
- solid state
- quantum dots
- human milk
- low cost
- low birth weight
- preterm birth
- mass spectrometry