One-Pot, Highly Stereoselective Synthesis of Dithioacetal-α,α-Diglycosides.

Maria F Céspedes DávilaJérémy P SchneiderAmélie GodardDamien HazelardPhilippe Compain

Published in: Molecules (Basel, Switzerland) (2018)

A one-step access to dithioacetal-α,α-diglycosides is reported. The synthetic strategy is based on the thioacetalization of aldehydes or ketones via highly stereoselective ring-opening of 1,6 anhydrosugars with bis(trimethylsilyl)sulfide.

Keyphrases

ionic liquid