Expounding the Initial Alloying Behavior of Na-K Liquid Alloy Electrodes.

Primary electrodeposition is an accepted strategy to elucidate the nucleation and growth kinetics of metal electrodes. Nevertheless, when confronted with the phase transition process caused by bi-active metals such as NaK liquid alloys, the research process becomes complex and elusive. Herein, we have reduced the intricate issues to relatively simple initial alloying behaviors. Two exchange diffusion mechanisms of the Na atom embedded in K crystals and K atom embedded in Na crystals are investigated by first-principles density functional theory (DFT) calculation and mechanical simulation. As a result, the process of embedding the Na atom in K crystals shows a better thermodynamic stability and lower activation barrier and structural stress than those of the other. The abovementioned conclusions are further proved by stepwise Na and K electrodeposition experiments, and the prepared NaK alloy electrode displays excellent electrochemical performance. Our findings correlate the original alloying mechanism model specification with electrodeposition experimental verification and provide strategies to achieve controllable NaK electrode construction.