Hydrostatic Pressure-Controllable Chiroptical Properties of Chiral Perylene Bisimide Dyes: A Chiral Aggregation Case.

Hydrostatically pressurized spectroscopic and lifetime decay analyses of optically active perylene bisimides were demonstrated in the pressure range of 0.1-320 MPa to show a π-stacked aggregation. The hydrostatic pressure-induced excitation and circular dichroism spectral changes of the fluorescence perylene dye enabled us to differentiate the slight pressure-sensitive aggregates. This work will lead to a new strategy for creating a pressure-responsive supramolecular polymerization material.