Recent Progress on Photocatalytic Synthesis of Ester Derivatives and Reaction Mechanisms.
Yiqiang DengTianbao YangHui WangChong YangLihua ChengShuang-Feng YinNobuaki KambeRenhua QiuPublished in: Topics in current chemistry (Cham) (2021)
Esters and their derivatives are distributed widely in natural products, pharmaceuticals, fine chemicals and other fields. Esters are important building blocks in pharmaceuticals such as clopidogrel, methylphenidate, fenofibrate, travoprost, prasugrel, oseltamivir, eszopiclone and fluticasone. Therefore, esterification reaction becomes more and more popular in the photochemical field. In this review, we highlight three types of reactions to synthesize esters using photochemical strategies. The reaction mechanisms involve mainly single electron transfer, energy transfer or other radical procedures.