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High-performance ultra-violet phototransistors based on CVT-grown high quality SnS 2 flakes.

Haoting YingXin LiYutong WuYi YaoJunhua XiWeitao SuChengchao JinMinxuan XuZhiwei HeQi Zhang
Published in: Nanoscale advances (2019)
van der Waals layered two-dimensional (2D) metal dichalcogenides, such as SnS 2 , have garnered great interest owing to their new physics in the ultrathin limit, and become potential candidates for the next-generation electronics and/or optoelectronics fields. Herein, we report high-performance UV photodetectors established on high quality SnS 2 flakes and address the relatively lower photodetection capability of the thinner flakes via a compatible gate-controlling strategy. SnS 2 flakes with different thicknesses were mechanically exfoliated from CVT-grown high-quality 2H-SnS 2 single crystals. The photodetectors fabricated using SnS 2 flakes reveal a desired response performance ( R λ ≈ 112 A W -1 , EQE ≈ 3.7 × 10 4 %, and D * ≈ 1.18 × 10 11 Jones) under UV light with a very low power density (0.2 mW cm -2 @ 365 nm). Specifically, SnS 2 flakes present a positive thickness-dependent photodetection behavior caused by the enhanced light absorption capacity of thicker samples. Fortunately, the responsivity of thin SnS 2 flakes ( e.g. ∼15 nm) could be indeed enhanced to ∼140 A W -1 under a gate bias of +20 V, reaching the performance level of thicker samples without gate bias ( e.g. ∼144 A W -1 for a ∼60 nm flake). Our results offer an efficient way to choose 2D crystals with controllable thicknesses as optimal candidates for desirable optoelectronic devices.
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