Solar CO 2 reduction using a molecular Re(I) catalyst grafted on SiO 2 via amide and alkyl amine linkages.

Heterogenized molecular catalysts have shown interesting activities in different chemical transformations. In our previous studies, a molecular catalyst, Re(bpy)(CO) 3 Cl where bpy is 2,2'-bipyridine, was covalently attached to silica surfaces via an amide linkage for use in photocatalytic CO 2 reduction. Derivatizing the bpy ligand with electron-withdrawing amide groups led to detrimental effects on the catalytic activity of Re(bpy)(CO) 3 Cl. In this study, an alkyl amine linkage is utilized to attach Re(bpy)(CO) 3 Cl onto SiO 2 in order to eliminate the detrimental effects of the amide linkage by breaking the conjugation between the bpy ligand and the amide group. However, the heterogenized Re(I) catalyst containing the alkyl amine linkage demonstrates even lower activity than the one containing the amide linkage in photocatalytic CO 2 reduction. Infrared studies suggest that the presence of the basic amine group led to the formation of a photocatalytically inactive Re(I)-OH species on SiO 2 . Furthermore, the amine group likely contributes to the stabilization of a surface Re(I)-carboxylato species formed upon light irradiation, resulting in the low activity of the heterogenized Re(I) catalyst containing the alkyl amine linkage.