Graphene oxide-ferrite hybrid framework as enhanced broadband absorption in gigahertz frequencies.

The present investigation is focused on the in-situ synthesis of Graphene oxide (GO)-ferrite nanoparticle hybrid framework by gel-combustion method followed by fabrication of homogeneous, structurally stable thin (~100-120 μm) hybrid-polyurethane coating on a metallic aluminum substrate and its application on the properties of broadband absorption over the microwave frequency region. Microstructure studies of hybrid materials illustrated that small sized ferrite nanoparticles (~17 nm) are grafted on and through the graphene layers, which forms a homogeneous coating thereby. The hybrid-nanocomposite coating demonstrated superior broadband absorption properties with absorptivity higher than 90% throughout a bandwidth of ~6 GHz, and moreover, it was found that with increased loading of GO in the nanocomposite, the bandwidth range of absorption frequency increases with enhanced absorptivity. The real part and imaginary part of the surface impedance values of the coating was obtained as 377 Ω and 0 Ω, respectively, which imply that the free-space impedance of the hybrid-nanocomposite coating is matching correctly. The nanocomposite coating showed ultra-high absorptivity over the frequency band of 8-12 GHz, which has numerous practical applications as radar absorbing materials (RAM), stealth technology, electromagnetic shielding, and radiated electromagnetic interference (EMI) management in onboard spacecraft and many more.