Magnetic porous biochar as a renewable and highly effective adsorbent for the removal of tetracycline hydrochloride in water.

In this study, discarded cigarette butts were used as a precursor for preparing magnetic porous biochar with a facile annealing method. The magnetic porous biochar was applied to remove tetracycline hydrochloride (TCH) from aqueous solution. It exhibited excellent adsorption capacity for TCH, which was much higher than various similar materials reported. At the same time, the adsorption kinetics and adsorption isotherms of TCH were well fitted to the pseudo-second-order models and Freundlich models, respectively. The thermodynamics experiments proved that the adsorption on magnetic porous biochar was an endothermic reaction. Furthermore, the adsorption mechanism was explored, and the outstanding adsorption ability was mainly dependent on the pore filling effect, electrostatic interaction, and π-π interaction. By using the magnetic porous biochar, the real water samples were treated and high removal efficiency to TCH was obtained. What's more, the excellent reusability endowed the magnetic porous biochar with great potential as adsorbents for practical application.