Dysprosium Single-Molecule Magnets with Bulky Schiff Base Ligands: Modification of the Slow Relaxation of the Magnetization by Substituent Change.
Jérôme LongIvan V BasalovNatalia V ForosenkoKonstantin A LyssenkoEkaterina MamontovaAnton V CherkasovMarko DamjanovićLiviu F ChibotaruYannick GuariJoulia LarionovaAlexander A TrifonovPublished in: Chemistry (Weinheim an der Bergstrasse, Germany) (2018)
The synthesis, and magnetic and photoluminescence investigations of two bifunctional dysprosium complexes based on tridentate Schiff base ligands is reported. Magnetic investigations reveal a genuine single-molecule magnet (SMM) behavior, with out-of-phase signals up to 60 K, and tunable emission arising from the Schiff base ligands.